NatureModernglobalmedium confidence

Unsweetened, dry cocoa powder can contain up to approximately 200 mg of caffeine per cup.

Notes on verification

USDA FoodData Central data supports ~198 mg caffeine per cup (86g) of unsweetened cocoa powder, corroborated by multiple independent secondary sources, though all trace back to the same USDA measurement. [cascade flags: wikipedia_dropped_other_sources_exist | tier=bronze indep_score=0.525 clusters=3 claim_tier=notable | framework convergence=single on USDA FoodData Central nutrient database entry for unsweetened cocoa powder (upstreams: USDA FoodData Central (SR Legacy 169593, 'Cocoa, dry powder, unsweetened')) — publishers independent, evidence may not be | kind=empirical eligibility=high]

Sources